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Duplex S32205/F60

Material: Grade S32205, DIN 1.4462, F60
S32205 duplex stainless steel, its international standard code is UNS S32205. As the representative of the second generation of duplex stainless steel, it has completely replaced the early UNS S31803 and become the mainstream material in the industry.
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Duplex S32205 Introduction:

S32205 Duplex Stainless Steel Tube/Plate (UNS S32205)


S32205 duplex stainless steel (UNS S32205) is a second-generation duplex alloy engineered to deliver superior strength and chloride resistance. With a balanced austenitic-ferritic microstructure, this s32205 material exceeds conventional stainless steels in:

  • Yield strength (2× higher than 316L).

  • Stress corrosion cracking (SCC) resistance.

  • Pitting/crevice corrosion resistance (PREN ≥ 35).


UNS S32205 and ASTM A182 F60 is a duplex grade with a ferritic-austenitic microstructure consists of around 40-50% ferrite in the annealed condition.


Certification Standards and Specifications

  1. Sheets/Plates and strips: ASTM A240 and ASME SA240;

  2. Bars/Rounds: ASTM A276 and ASME SA276;

  3. Seamless and welded pipes/tubes: ASTM A789 and ASME SA789; ASTM A790 and ASME SA790; ASTM A312 and ASME SA312.


Duplex S32205 Steel Features

Duplex S32205 has the high strength of the ferritic grades whilst retaining the corrosion resistance of the austenitic grades.


UNS S32205 has superior resistance to chloride pitting and crevice corrosion as compared to 317L stainless steel, Alloy 2205(UNS S32205) has outstanding corrosion resistance to seawater and most concentrations of sulphuric acid. 


In addition, 2205 duplex stainless is also resistant to sulphide stress corrosion cracking (sour-gas environments). These high quality corrosion resistance, resistance to stress corrosion cracking and therefore performance are widely attributed to its high levels of chromium present as well as nitrogen and molybdenum.


S32205 Chemical Composition(%)

Grade

C≤

Mn≤

P≤

S≤

Si≤

Ni

Cr

Mo

N

S32205

0.04

2

0.03

0.02

1.00

4.5–6.5

22.0–23.0

3.0–3.5

0.14–0.20


S32205 Mechanical Properties

Grade

Tensile, min, ksi[MPa]

Yield, min, ksi[MPa]

Elongation, %(min)

Hardness, HB(max)

S32205

95 [655]

65 [450]

25

293


S32205 Physical Properties

Code

2205

Density (kg/m3)

7800

Elastic Modulus (GPa)

190

Thermal Expansion (μm/m/°C)

0-100°C

13.7

0-315°C

14.2

0-538°C

-

Thermal Conductivity (W/m.K)

at 100°C

19

at 500°C

-

Specific Heat ( J/kg.K)

0-100°C

418

Electrical Resistivity (nΩ.m)

850


S32205 Equivalent Grades

This is a comparison table of grades for S32205 Duplex Steel, comparing functionally similar materials.

STANDARD

WERKSTOFF NR.

UNS

EN

Duplex S32205

1.4462

S32205

X2CrNiMoN22-5-3


Duplex Steel S32205 ASTM Specifications


Product Name

Standard

Show

Pipe SMLS& Welded

ASTM A790

Duplex Steel S32205 Pipe

Tube SMLS& Welded

ASTM A789

Duplex Steel S32205 Tube

Sheet/Plate

ASTM A240

Duplex Steel S32205 Sheets and Plates

Bar /Rod

ASTM A276/A479

Duplex Steel S32205 Bars and Rounds

Forging /Flange

ASTM A182 F60

Duplex Steel S32205 Flange

BW Fittings

ASTM A815

Duplex Steel S32205 BW Fittings



S31803 vs S32205


Here's a precise technical comparison of S31803 vs S32205 duplex stainless steels, based on international standards (ASTM/ISO) and industrial data:

Parameter

UNS S31803 (1st Gen Duplex)

UNS S32205 (2nd Gen Duplex)

PREN①

31-32

≥35

Nitrogen (N) Content

0.08-0.20%

0.14-0.20% (Tighter control)

Critical Pitting Temp.

≤25°C (ASTM G48)

≥35°C (ASTM G48)

Yield Strength

≥450 MPa

≥450 MPa

Chloride Resistance

Moderate

Superior

H₂S Service Limit

≤0.1 psi H₂S (pH≥4.5)

≤3 psi H₂S (pH≥3.5)

Modern Applications

Legacy systems

Current industry standard


Why S32205 Replaced S31803?


  1. Higher Corrosion Resistance

    1. Higher nitrogen content in S32205 increases PREN by 12%, extending service life in: Seawater and HCl/Cl⁻ environments.

  2. Improved Weldability

    1. S32205's controlled N range (0.14-0.20%) prevents:

      1. Excessive ferrite in HAZ (Heat-Affected Zones)

      2. Secondary phase precipitation

      3. Maintains 30-55% ferrite in welds (vs 20-70% in S31803).

  3. Standardization Shift

    1. Major standards ASTM A790/A240 now specify S32205 as baseline: s31803 remains acceptable only if properties meet S32205 minima.


New projects specify S32205 for critical service.


S32205 Application


S31803 and S32205 duplex steel are mainly used in:

  • Chemical industry, paper industry, oil refining industry;

  • Seawater desalination equipment, seawater system;

  • Chemical tanker cargo hold and piping system;

  • Fire and explosion-proof walls of offshore platforms;

  • Bridges, structural design components;

  • Pressure vessels, heat exchangers;

  • Turbine blades and drive shafts;

  • Papermaking machinery, pulp equipment, etc.


About S32205 Resource

JN Alloy Products


JN Alloy is a distributor and product manufacturer of stainless steel, duplex steel, and nickel alloy.
Tel: +86 19339900211
Add: Stainless steel Market 289, Xinwu District , Wuxi, China
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