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Monel 400

Material: Monel 400, UNS N04400, 2.4360
Monel alloy 400 (UNS N04400) is a solid-solution alloy that can be hardened only by cold working. This alloy has excellent corrosion resistance in hydrofluoric acid and fluorine gas medium, and also has excellent corrosion resistance in hot concentrated lye.
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What Is Monel 400?

Monel400 (UNS N04400) is a nickel-copper alloy with a composition ratio of Ni67-Cu23. It is currently the nickel-copper corrosion-resistant alloy with the largest usage, the widest application, and the best overall performance.


Alloy 400 monel has excellent corrosion resistance in hydrofluoric acid and fluorine gas media, and also has excellent corrosion resistance to hot concentrated alkali solution. It is also resistant to corrosion by neutral solutions, water, seawater, atmosphere, organic compounds, etc. An important feature of this alloy is that it generally does not produce stress corrosion cracks and has good cutting performance!


Monel alloy 400 (UNS N04400) is a solid-solution alloy that can be hardened only by cold working. This alloy has excellent corrosion resistance in hydrofluoric acid and fluorine gas medium, and also has excellent corrosion resistance in hot concentrated lye. At the same time, it is also resistant to corrosion by neutral solutions, water, seawater, atmosphere, organic compounds, etc. An important feature of this alloy is that it generally does not produce stress corrosion cracking and has good machinability. It is a corrosion-resistant alloy with the largest amount, the most widely used and excellent comprehensive properties.


Alloy 400 is widely used in many fields, especially marine and chemical processing. Typical applications are pump and propeller shafts; marine fixtures and fasteners; electrical and electronic components; springs; chemical processing equipment; gasoline and fresh water tanks; crude petroleum stills,process vessels and piping; boiler feedwater heaters andother heat exchangers; and deaerating heaters.


Monel 400 Chemical Composition


Grade

C≤

Mn≤

Si

S≤

Cu

Fe≤

Ni≤

Monel400

0.3

2

0.5

0.024

28.0-34.0

2.5

63


Monel 400 Mechanical Properties


Product Form

Condition

Tensile(Ksi)

.2% Yield (Ksi)

Elongation(%)

Hardness(HRB)

Rod&Bar

Annealed

75-90

25-50

60-35

60-80

Rod&Bar

Cold-Drawn Stress Relieved

84-120

55-100

40-22

85-20HRC

Plate

Annealed

70-85

28-50

50-35

60-76

Sheet

Annealed

70-85

30-45

45-35

65-80

Tube&Pipe Seamless

Annealed

70-85

25-45

50-35

75 max*


Monel 400 Physical Properties


Density

8.80g/cm3

Elastic modulus

26 000 ksi

Heating energy

0.427 J/g-°C

Coefficient of Thermal Expansion

70-200F

7.7

70-400F

8.6

70-800 F

8.9

70-1000F

9.1


Monel 400 ASTM Specifications


Product

Standard

Show

Monel 400 Seamless Pipe

ASTM B165

Monel 400 Seamless Pipe

Monel 400 Welded Pipe

ASTM B474

Monel 400 Welded Pipe

Monel 400 Seamless Tube

ASTM B163/B165

Monel 400 Seamless Tube

Monel 400 Sheet

ASTM B127

Monel 400 Sheet

Monel 400 Bars

ASTM B164

Monel 400 Bars

Monel 400 Forging

ASTM B564

Monel 400 Forging

Monel 400 Fittings

ASTM B366

Monel 400 Fittings


JN Monel400 material has excellent hot and cold processing properties. Alloy 400 Monel products are complete. We can provide plates, strips, tubes, wires, rods, forgings, fasteners, flanges, pipe fittings and other products.


Monel 400 Equivalent Grades


STANDARD

WERKSTOFF NR.

UNS

JIS

BS

GOST

AFNOR

EN

Monel 400

2.4360

N04400

NW 4400

NA 13

МНЖМц 28-2,5-1,5

NU-30M

NiCu30Fe


Monel Alloy 400 Corrosion Resistance


Monel 400 alloy has excellent corrosion resistance in fluorine gas, hydrochloric acid, sulfuric acid, hydrofluoric acid and their derivatives, and is one of the few important materials that can resist hydrofluoric acid.


Sulfuric acid environment:

Alloy 400 is corrosion-resistant in sulfuric acid with a concentration of less than 85%.


Aqueous corrosion:

Under most water corrosion conditions, Monel 400 alloy not only has excellent corrosion resistance, but also rarely suffers from pitting corrosion and stress corrosion, with a corrosion rate of less than 0.025mm/a.


High temperature corrosion:

The maximum temperature of alloy 400 in continuous operation in air is generally around 400C, and in high-temperature steam, the corrosion rate is less than 0.026mm/a.


Ammonia:

Due to the high nickel content of Monel 400 alloy, it can resist corrosion under anhydrous ammonia and ammoniated conditions below 585°C.


Heat Treatment

Monel 400 material annealing temperature is generally between 700 and 900°C, and the best effect is achieved at 825°C. Rapid air cooling after treatment can achieve good corrosion resistance. The purpose of this is to soften the material after forging to keep the material relatively fine particles. The annealing temperature and time are directly related to the final grain size, so the annealing parameters should be carefully considered.


Welding


Monel400 can be welded by gas tungsten arc, gas metal arc welding and shielded gas metal arc welding.


Before welding, clean the groove and electrode with acetone, and use GTAW as the welding method. Use ERNiCu-7 as the welding wire and ENICU-7 as the welding electrode.


400 Monel does not require preheating before welding, nor does it require post-weld heat treatment, because the strength of the material is improved after welding, which is beneficial for future use.


The fluidity of the molten metal in 400 material welding is poor, so a large groove angle (60-70°) should be used to allow the welding wire to fill the weld.


Monel 400 Applications


  • Feed water and steam generator tubing

  • Brine heaters, sea water scrubbers in tanker inert gas systems

  • Sulfuric acid and hydrofluoric acid alkylation plants

  • Pickling bat heating coils

  • Heat exchangers in a variety of industries

  • Transfer piping from oil refinery crude columns

  •  Plant for the refining of uranium and isotope separation in the production of nuclear fuel

  • Monoethanolamine (MEA) reboiling tube

  • Cladding for the upper areas of oil refinery crude columns


FAQs


Is Alloy 400 the same as Monel?


Yes. "Monel 400" is the original trade name. "Alloy 400" is the common industry designation for the same material. It is also standardized as:

  • UNS N04400

  • ASTM B127, B164, B165

  • EN 2.4360 / 2.4361


In conclusion,  "Monel 400" and "Alloy 400" refer to the identical nickel-copper alloy. "Monel" alone is ambiguous, as it refers to a series of alloys.


Is Monel 400 magnetic?


No. Monel 400 is essentially non-magnetic at all temperatures.

Its primary constituents are nickel and copper, both inherently non-ferromagnetic elements. Minor iron content is insufficient to impart significant magnetic permeability. While non-magnetic like austenitic stainless steels, very slight magnetic response might be detectable with extremely sensitive instruments due to trace impurities or cold working, but it is not considered a magnetic material for practical engineering purposes.


How to Weld Monel 400?


Welding Monel 400 requires specific techniques to maintain its corrosion resistance and mechanical properties.


Aspect

Recommendation

Reason

Cleanliness

Critical: Degrease + stainless steel wire brush

Prevents contamination leading to porosity/cracking

Welding Processes

GTAW (TIG): Preferred
GMAW (MIG): Suitable
SMAW (Stick): Possible with specific electrodes

Best control with TIG; MIG requires spray transfer

Filler Metal

ENiCu-7 (AWS A5.11/5.14)
ERNiCu-7 (AWS A5.14)

Matches base metal composition (e.g., Monel 60, 70, or 190)

Joint Design

Wider gaps + larger root openings vs steel

Accommodates higher thermal expansion

Preheat/Interpass Temp

Not usually required
Max interpass: 150°C (300°F)

Prevents excessive grain growth

Heat Input

Low to Moderate

Maintains corrosion resistance & mechanical properties

Technique

Stringer beads
Avoid weaving
Back-purging for critical welds

Minimizes heat input and oxidation

Post-Weld Treatment

Not required for most applications

Stress relief may be needed for severe service conditions


400 Monel Alloy Standards

ASTM B165.PDF

ASTM B474.pdf

ASTM B163.pdf

ASTM B127.pdf

ASTM B164.pdf

ASTM B564.pdf

ASTM B366.pdf


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